Question

  • Question: A block of copper and one of aluminum each has a mass of 1 kg. Initially, the temperature of the copper block is 150 ° C and the temperature of the aluminum block is 50 ° C. The blocks are isolated from the environment. They put in thermal contact with each other. Find the equilibrium temperature, the total entropy change and determine if the process isA block of copper and one of aluminum each has a mass of 1 kg. Initially, the temperature of the copper block is 150 ° C and the temperature of the aluminum block is 50 ° C. The blocks are isolated from the environment. They put in thermal contact with each other. Find the equilibrium temperature, the total entropy change and determine if the process is reversible, irreversible and impossible. The specific heat of copper is 0.385 kJ / kg Ky and the specific heat of aluminum is 0.9 kJ / kg K.

Answer

Solution :
Given Data :-
Mass of copper and aluminum m = mcu = mA = 1 kg
Initial temperature of copper (Tcu)1 = 150C = 423K
Initial temperature of aluminum (TAI)1 = 50C = 323 K
The specific heat of copper Cou= 0.385 kJ/kg.K
The specific heat of aluminum CAL = 0.9 kJ/kg.K
There is no work or heat transfer with environment, so W = AQ = 0
Applying first law of thermodynamics for this system:
\therefore \Delta Q-W=\Delta U
As, AQ =W=0+ AU = 0
\textup{where, } \Delta U \textup{ is change in internal energies of system.}
\therefore \Delta U_{Cu}+\Delta U_{Al}=0
\therefore [mC(T_2-T_1)]_{Cu}+[mC(T_2-T_1)]_{Al}=0
As we know (Tcu)2 = (TA12 = T2
\therefore [1(0.385)(T_2-150)]+[1(0.9)(T_2-50)]=0
\therefore 1.285\, T_2\, -102.75=0
{\color{DarkBlue} \therefore \, T_2\,=79.9611^{\circ}\, C=352.961\, K}\, \, \, \, \textbf{(\textup{Equillibrium temperature})}
\textup{The entropy change for solid object is given as : }\Delta S=mC\ln \left (\frac{T_2}{T_1} \right )
\textup{Total entropy change of system is given as : }\Delta S=\Delta S_{Cu}+\Delta S_{Al}
\Delta S=\left [mC \ln \left ( \frac{T_2}{T_1} \right ) \right ]_{Cu}+\left [mC \ln \left ( \frac{T_2}{T_1} \right ) \right ]_{Al}
352.9611 AS = 1(0.385) In (4231+ (0.5) 352.9611 323 )
{\color{DarkBlue} \Delta S=0.01014446\, \,\textup{ kJ/K}=10.14446\, \, \textup{ J/K}} \, \, \textbf{(Total entropy change)}
\textup{As the total entropy change is greater than zero. }(\Delta S)>0
\textup{Hence the process is\textbf{ irreversible.}}
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